The Missing Member of the Partially O-Alkylated Resorcinarene Family: Synthesis and Conformation of Methyl Tetramethoxy Resorcinarene
Finna-arvio
The Missing Member of the Partially O-Alkylated Resorcinarene Family: Synthesis and Conformation of Methyl Tetramethoxy Resorcinarene
dx.doi.org/10.1021/ol400118t
(Jyväskylän yliopisto - JYX)
final draftorglett 2013 15 1096.pdf
(Jyväskylän yliopisto - JYX)
An improved Lewis acid catalyzed synthesis method for methyl tetramethoxy resorcinarene is described, which produced the missing lower rim methyl derivative of this partially O-alkylated resorcinarene family. Structural characterization by means of variable temperature NMR experiments and single crystal X-ray diffraction studies furthermore revealed that the resorcinarene core adopts different conformations in the solid state and in solution.
Tallennettuna:
Kieli |
englanti |
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Sarja | Organic Letters, 5 |
Aiheet | |
ISSN |
1523-7060 |