Single Crystal Sub-Nanometer Sized Cu6(SR)6 Clusters : Structure, Photophysical Properties, and Electrochemical Sensing

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Single Crystal Sub-Nanometer Sized Cu6(SR)6 Clusters : Structure, Photophysical Properties, and Electrochemical Sensing

Organic ligand-protected metal nanoclusters have attracted extensively attention owing to their atomically precise composition, determined atom-packing structure and the fascinating properties and promising applications. To date, most research has been focused on thiol-stabilized gold and silver nanoclusters and their single crystal structures. Here the single crystal copper nanocluster species (Cu6(SC7H4NO)6) determined by X-ray crystallography and mass spectrometry is presented. The hexanuclear copper core is a distorted octahedron surrounded by six mercaptobenzoxazole ligands as protecting units through a simple bridging bonding motif. Density functional theory (DFT) calculations provide insight into the electronic structure and show the cluster can be viewed as an open-shell nanocluster. The UV–vis spectra are analyzed using time-dependent DFT and illustrates high-intensity transitions involving primarily ligand states. Furthermore, the as-synthesized copper clusters can serve as promising nonenzymatic sensing materials for high sensitive and selective detection of H2O2.

Tallennettuna:
Kieli
englanti
Aiheet
ISSN
2198-3844