Kaikki aineistot
Lisää
Väkivaltatilanteet ja väkivallan uhka on yleistä sosiaali- ja terveydenhuollon yksiköissä. Huomattavan moni kehitysvammaisten hoitaja altistuu työssään väkivallalle. Väkivallan jatkuva uhka ja väkivallan kohteena oleminen vaikuttaa hoitajien työssä jaksamiseen ja työhyvinvointiin. Sosiaali- ja terveydenhuollossa asiakkaita ei voida valita, vaan kaikki asiakkaat täytyy hoitaa. Tutkimuksen tarkoituksena oli kuvata henkilökunnan kirjaamia HaiPro-työturvallisuusilmoituksia Pohjois-Suomessa sijaitsevan kehitysvammaisten kuntoutusyksikön asiakkaiden kohdistamasta väkivallasta henkilökuntaan kohtaan. Tutkimuksen tavoitteena oli tuottaa uutta tietoa asiakkaiden aiheuttamista väkivaltatilanteista. Tutkimustuloksia hyödyntämällä kehitysvammaisten kuntoutusyksikön henkilökunta miettii keinoja väkivaltatilanteiden vähentämiseksi ja toiminnan kehittämiseksi. Kehitysvammaisten kuntoutusyksikölle on suunnitelmissa rakentaa lähivuosina uudet tilat. Tutkimustuloksia hyödynnetään uusien tilojen- sekä toiminnallisessa suunnittelussa. Tutkimuksen aineistona käytin HaiPro–ohjelmaan kirjattuja työturvallisuusilmoituksia, joissa vaarantyypiksi oli valittu väkivalta. Ilmoituksia oli yhteensä 31 kappaletta. Tutkimustuloksien perusteella asiakkaiden aiheuttamia väkivaltatilanteita henkilökuntaa kohtaan oli eniten perjantaista sunnuntaihin. Eniten väkivaltatilanteita oli asiakkaiden ruokailujen aikana ja 35 prosenttia kaikista väkivaltatapahtumista sijoittui kello 11:20 – 12:40 väliselle ajalle. Tyypillisin väkivallan muoto oli raapiminen. Monissa työturvallisuusilmoituksissa ilmoittaja oli kirjannut ilmoitukseen väkivaltatilanteen tapahtuneen yllättäen. Ilmoittajat pystyivät työturvallisuusilmoituksessa kertomaan oman näkemyksensä, miten heidän mielestä vastaavanlainen tapahtuma voitaisiin estää tulevaisuudessa. Yleisimmin toivottiin asiakkaalle lääkityksen lisäystä tai lääkityksen muutoksia. Yhdeksästä ilmoituksesta puuttui tai ilmoittaja ei osannut sanoa, miten vastaavanlainen tilanne voitaisiin estää. Ilmoittajat myös kokivat, että paremmalla ennakoinnilla voidaan estää vastaavanlaiset väkivaltatilanteet.
Tässä opinnäytetyössä tarkasteltiin Rovaniemen Verkko Oy:n jakeluverkon kuormituskehitystä pitkällä aikavälillä. Vuoteen 2030 saakka ulottuvan kuormitusennusteen tarkoituksena oli tutkia sähköasemien lähtöjen kapasiteettia yhtiön toimintaympäristön muuttuessa. Toimintaympäristön muutosten tarkastelu pohjautui väestössä, kaavoituksessa, rakennuskannassa ja kuluttajien ominaiskulutuksissa tapahtuviin muutoksiin. Ennusteen perusteella suoritettu laskenta osoitti, että vuoteen 2030 mennessä sähköasemien useiden lähtöjen kapasiteetti loppuu kesken. Sähköasemien lähtöjen määrää on lisättävä, jotta yhtiö voi luotettavasti siirtää sähköä asiakkailleen. Tuloksia on kuitenkin pidettävä vain suuntaa-antavina, koska verkkotietojärjestelmän verkkomallin lähtötiedot eivät vastanneet todellisen verkon kuormitustilaa. Kuormitusennusteen epävarmuutta lisäävät myös olettamuksiin perustuva väestöennuste ja se, että Rovaniemen kaavoituksen lopullinen suunta selviää vasta lähivuosina. Varsinaisen kuormitusennusteen lisäksi työssä tarkasteltiin myös muutamia seikkoja, jotka voivat tulevaisuudessa vaikuttaa sähköenergian käyttöön ja sähköverkon kuormitushuippuihin. Käsiteltävinä olivat sähköautot, energiansäästölamput, matalaenergiarakentaminen, pientuotanto, energiaverotus ja sähköenergian hintakehitys.
This doctorial thesis offers a guideline for modelling gas-liquid flow in stirred tanks with computational fluid dynamics (CFD). Particularly the effect of varying physical properties and industrial operating conditions is highlighted. The most important thing in modelling mass transfer in stirred vessels is the accurate prediction of local bubble size. Population balances for bubbles are needed for accurate description of the local mass transfer rate. There are many pitfalls in gas-liquid modelling at the transitional turbulence regime, and they need to be recognised and dealt with at a reasonable computational cost. Details of the work are presented in the included publications, this thesis sums up the findings. Backbone of this thesis is the experimental work done on 14 and 200 dm³ vessels. Experimental techniques were compared in making bubble size distribution (BSD) measurements. A variety of experiments were made to investigate: physical properties, vapour-liquid equilibrium, gas hold-up, gas-liquid mass transfer, bubble size distributions, local mixing times, flow fields and bubble swarm interactions. Parameters for a number of phenomenological models were fitted with a computationally less demanding multiblock model and were then used to simulate stirred reactors with CFD. The early systems were lean dispersions of low viscosity; at the end of this work opaque shear thinning G-L dispersions were modelled. The effect of impeller geometry on G-L mass transfer was studied by simulating three impeller geometries. There were no differences in the volumetric mass transfer rate between the impellers, although the flow patters and gas hold-up showed clear differences between the impellers. Heterogeneous behaviour like gas slug creation and reactor dead-spaces were successfully modelled. The simulated dispersions were highly heterogeneous: 50% of mass transfer took place in less than 10% of the reactor volume. A xanthan fermentation batch lasting for days was modelled; the reaction speed was bottlenecked by both mixing and mass transfer. These findings strongly support the use of spatially detailed models over ideal mixing assumption.
We report the fabrication and characterization of supercapacitors prepared on a flexible substrate using a printable, high-viscosity carbon nanotube (CNT) ink. The CNT-hemicellulose composite ink was prepared using ultrasonication and applied on the substrate with a doctor blade. Aqueous sodium chloride was used as electrolyte. The capacitance of the supercapacitors was 16 mF for a device size of 2 cm2. The measurements were carried out in accordance to an international standard for electric double layer capacitors.
Piezoelectric thin-film sensors are suitable for a wide range of applications from physiological measurements to industrial monitoring systems. The use of flexible materials in combination with high-throughput printing technologies enables cost-effective manufacturing of custom-designed, highly integratable piezoelectric sensors. This type of sensor can, for instance, improve industrial process control or enable the embedding of ubiquitous sensors in our living environment to improve quality of life. Here, we discuss the benefits, challenges and potential applications of piezoelectric thin-film sensors. The piezoelectric sensor elements are fabricated by printing electrodes on both sides of unmetallized poly(vinylidene fluoride) film. We show that materials which are solution processable in low temperatures, biocompatible and environmental friendly are suitable for use as electrode materials in piezoelectric sensors.
We report ecological and low-cost carbon nanotube (CNT) supercapacitors fabricated using a simple, scalable solution processing method, where the use of a highly porous and electrically conductive active material eliminates the need for a current collector. Electrodes were fabricated on a poly(ethylene terephthalate) substrate from a printable multi-wall CNT ink, where the CNTs are solubilized in water using xylan as a dispersion agent. The dispersion method facilitates a very high concentration of CNTs in the ink. Supercapacitors were assembled using a paper separator and an aqueous NaCl electrolyte and the devices were characterized with a galvanostatic discharge method defined by an industrial standard. The capacitance of the 2 cm(2) devices was 6 mF/cm(2) (2.3 F/g) and equivalent series resistance 80 Omega. Low-cost supercapacitors fabricated from safe and environmentally friendly materials have potential applications as energy storage devices in ubiquitous and autonomous intelligence as well as in disposable low-end products.
Homogenization of reacting flows by mixing is often important in order to achieve high reaction rates. Mechanical RANSagitation is the usual way to homogenize fluids used in industry. When supplied to fluid media, mechanical energy creates turbulence that facilitates mixing. A stirred tank reactor (STR) is a conventional operational unit designed to provide sufficient mixing and suitable conditions for reactions. The design of STRs depend on the operating conditions and properties of the reacting flows. Various types of stirred reactors are used in industry that are different in geometry but share the same principles of multiphase flow, turbulence, interphase mass transfer, and reaction. Heterogeneous reactions demand extra attention, because the reaction rate is often limited by mass transfer. Mass transfer through interface boundary depends on mass transfer coefficient, interfacial contact area, through which species are transferred, and species concentration gradient. The mass transfer coefficient, on the other hand, depends on the physical properties of the fluid media and mixing rate at micro scale. In turbulent flow, micromixing is driven by a cascade of turbulent Kolmogorov eddies. In turn, the contact area between fluids is greatly dependent on bubble or droplet size distribution. Empirical correlations, describing the design parameters of mixed multiphase systems, such as gas hold-up, mixing power, volumetric mass transfer etc., in an STR are predominantly based on existing lab- and pilot-scale reactors. Therefore, the design and scale-up of agitated reactors is unreliable, especially for multiphase systems. In order to increase STRs performance, to make reactor design more reliable, to optimize operational conditions, and to improve existing STRs in industry, advanced mathematical tools are required that are capable of examining and testing engineering ideas in detail, preferably before building a laboratory-scale prototype and especially during the scale-up process. Computational fluid dynamics (CFD) can describe reacting flows in different geometries more accurately than conventional empirical correlations. Detailed information on reacting flows forms a powerful tool in reactor design and scale-up, finding of operational conditions, and studying STR performance under extreme conditions. Due to the nature of Eulerian mathematical approach to fluid flow description and limited spatial and temporal resolutions, CFD software comprises empirical parameters. Therefore, experimental validation of CFD models is crucial. Various intrusive and non-intrusive experimental methods have been invented and presented in literature to provide a trustworthy insight into fluid hydrodynamics. Each of them has a limited area of application and a combination of several measurement techniques is required to characterize reacting flows sufficiently to verify CFD models. The aim of this thesis was to develop a set of reliable, experimentally validated models capable to accurately describe multiphase reacting flows in agitated vessels. The modelled physical phenomena were added in a step-wise manner starting from a simple single-phase non-reacting flow in a standard STR and continuing to a multiphase fermentation process in large-scale draft tube OKTOP®9000 reactor. Applicable experimental techniques, such as particle image velocimetry (PIV), electrical impedance tomography (EIT), rheometry, gas hold-up, mixing power, and gas-liquid mass transfer measurements were used to obtain validation data. Several Reynolds-averaged Navier-Stokes (RANS) turbulence models were tested in a tall, round-bottomed STR equipped with a single Rushton turbine. The k-ɛ Realizable model was found to be the most feasible model for turbulence among the tested twoequation models and it produced the most accurate results in comparison to experiments in single phase mixing. In the dilute gas–liquid mixing case, bubbles drag force was modelled most accurately by using the Schiller-Naumann’s drag force model in combination with Lane’s turbulence modification factor. The drag force impact was found to dominate compared to non-drag forces. On the other hand, in the dense gas–liquid flow of spherical bubbles in STR, the dampening effect of the bubble swarms on liquid flow was simulated by the Roghair’s modification factor and included into the bubble drag force formula. The effect of the relative position of impeller blades to baffles on the simulated hydrodynamics via multiple reference frame (MRF) approach was assessed in single and multiphase mixing flows. The effect was found to be less significant in single phase but more evident in gas–liquid mixing. The simulated results at a fixed angular position of an impeller can be improved by averaging the hydrodynamic results simulated at the extreme positions of the impeller. The three-phase hydrodynamics of a gold concentrate leaching process in a batch STR was modelled. The gold concentrate suspended in agitated liquid flow revealed non- Newtonian rheology, which was used in the simulation. The rheological properties of the agitated suspended solids were mimicked experimentally by in a water solution of carboxylmethyl cellulose (CMC), the hydrodynamics of which was measured by particle image velocimetry (PIV). Electrical impedance tomography (EIT) was used to visualize local gas hold-up. Using the assumption of constant bubble size, the local volumetric mass transfer coefficient of oxygen was calculated, which can be used to improve the reliability of the scale-up when designing larger-scale leaching reactors. An experimental and numerical study of the effect of reagent feed location on the barium sulphate crystallization process was carried out in a semi-batch stirred reactor. The temporal development of crystallization was measured by the EIT technique. CFD modelling was applied to assess local hydrodynamics in a flat-bottomed stirred reactorequipped with a Rushton turbine. The effect of mixing, considered at macro and meso scales, was found to have a great impact on crystal size because the residence time distribution of the supersaturated concentration is a function of local mixing intensity in the feed area, as well as being a function of the global flow pattern of mixing. Scale-up of a draft tube reactor was performed from laboratory to industrial scale using CFD modelling. The same number of cells was used in the mesh in both scales to analyze the effect of spatial discretization on the resolved hydrodynamics and gas-liquid mass transfer. An aerobic fermentation process was simulated in the draft tube OKTOP reactor at industrial scale with a known power number. The Newtonian gas–liquid flow, agitated by an impeller of special design, was modelled with an updated drag force that included the effect of bubble swarms. At constant bubble size, the compensation of local volumetric power, which is usually underpredicted by RANS models, increased gas– liquid mass transfer insignificantly (by less than 5 %). However, calculation of the local bubble-size distribution increased the kLa value by 15 %. The simulation results of Pichia pastoris cell cultivation in industrial batch STR showed reasonable agreement against the experimental data obtained in an identical reactor at laboratory scale. The effect of the oxygenation rate on fermentation was found to increase biomass yield by shifting the metabolism from the fermentative path of sugar consumption to the oxidative path. Different models available in published literature for turbulence and interphase forces were validated in STRs of different geometries operated over a wide range of operational conditions at both laboratory (14 dm3) and industrial (800 m3) scales. These models can accurately describe the hydrodynamics and mass transfer, and the coupled reaction kinetics of heterogeneous reacting flows in STRs that are often encountered in chemical processes. Being more flexible than empirical correlations regarding reactor geometry, the CFD models can provide insightful information of great detail. Thus, they can significantly improve the accuracy and reliability of reactor design and scale-up, as well as take the troubleshooting and reactor configuration design to the next level.