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Today's intermediate-scale quantum computers, although imperfect, already perform computational tasks that are manifestly beyond the capabilities of modern classical supercomputers. However, so far, quantum-enabled large-scale solutions have been realized only for limited set of problems. Here a hybrid algorithm based on phase estimation and classical optimization of the circuit width and depth is employed for solving a specific class of large linear systems of equations ubiquitous to many areas of science and engineering. A classification of linear systems based on the entanglement properties of the associated phase-estimation unitary operation is introduced, enabling a highly efficient search for solutions that is facilitated by a straightforward matrix-to-circuit map. A 217-dimensional problem is implemented on several IBM quantum computer superconducting quantum processors, a record-breaking result for a linear system solved by a quantum computer. Demonstrated realisation sets a clear benchmark in the quest for the future quantum speedup in the linear systems of equations solution.
For the 68Zn + 112Sn reaction the Coulomb parameter Z1Z2 is equal to 1500 that is close to the threshold value for the appearance of quasifission process. It was found that mass-energy distributions of the reaction fragments differ significantly from those obtained in the 36Ar + 144Sm reaction leading to the formation of the same composite system of 180Hg at similar excitation energies of about 50 MeV. In the case of the reaction with 68Zn ions, the mass distribution of fissionlike fragments has a wide two-humped shape with maximum yields at 70 and 110 u for the light and heavy fragments, respectively, instead of 80 and 100 u observed in the fission of 180Hg formed in the 36Ar + 144Sm reaction. The difference is explained by an unexpectedly large contribution (more than 70%) of quasifission in the case of the 68Zn + 112Sn reaction.
180mTa is a naturally abundant quasistable nuclide and the longest-lived nuclear isomer known to date. It is of interest, among others, for the search for dark matter, for the development of a γ laser, and for astrophysics. So far, its excitation energy has not been measured directly but has been based on an evaluation of available nuclear reaction data. We have determined the excitation energy of this isomer with high accuracy using the Penning-trap mass spectrometer JYFLTRAP. The determined mass difference between the ground and isomeric states of 180Ta yields an excitation energy of 76.79(55) keV for 180mTa. This is the first direct measurement of the excitation energy and provides a better accuracy than that of the previous evaluation value, 75.3(14) keV.
Purpose: The study of asymmetric and symmetric fission of 180,182,183Hg and 178Pt nuclei as a function of their excitation energy and isospin. Methods: Mass-energy distributions of fission fragments of 180Hg, 178Pt (two protons less than 180Hg), and 182Hg (two neutrons more than 180Hg) formed in the 36Ar+144Sm,142Nd, and 40Ca+142Nd reactions were measured at energies near and above the Coulomb barrier. Fission of 183Hg obtained in the reaction of 40Ca with 143Nd was also investigated to see if one extra neutron could lead to dramatic changes in the fission process due to the shape-staggering effect in radii, known in 183Hg. The measurements were performed with the double-arm time-of-flight spectrometer CORSET. Results: The observed peculiarities in the fission fragment mass-energy distributions for all studied nuclei may be explained by the presence of a symmetric fission mode and three asymmetric fission modes, manifested by the different total kinetic energies and fragment mass splits. The yield of symmetric mode grows with increasing excitation energy of compound nucleus. Conclusions: The investigated properties of asymmetric fission of 180,182,183Hg and 178Pt nuclei point out the existence of well-deformed proton shell at Z≈36 and a less deformed proton shell at Z ≈ 46.
The dihalomethane–halide H2C(X)–X···X– (X = Cl, Br) halogen bonding was detected in a series of the cis-[PdX(CNCy){C(NHCy)═NHC6H2Me2NH2}]X•CH2X2 (X = Cl, Br) associates by single-crystal XRD followed by DFT calculations. Although ESP calculations demonstrated that the σ-hole of dichloromethane is the smallest among all halomethane solvents (the maximum electrostatic potential is only 2.6 kcal/mol), the theoretical DFT calculations followed by Bader’s QTAIM analysis (M06/DZP-DKH level of theory) confirmed the H2C(X)–X···X– halogen bond in both the solid-state and gas-phase optimized geometries. The estimated bonding energy in H2C(X)–X···X– is in the 1.9–2.8 kcal/mol range.
The structural, chemical, and electronic properties of epitaxial graphene films grown by thermal decomposition of the Si-face of a semi-insulating 6H-SiC substrate in an argon environment are studied by Raman spectroscopy, X-ray photoelectron spectroscopy and angle-resolved photoemission. It was demonstrated the possibility of fabrication of the gas and biosensors that is based on grown graphene films. The gas sensors are sufficiently sensitive to NO2 at low concentrations. The biosensor operation was checked using an immunochemical system comprising fluorescein dye and monoclonal anti fluorescein antibodies. The sensor detects fluorescein concentration on a level of 1-10 ng/mL and bovine serum albumin- fluorescein conjugate on a level of 1-5 ng/mL. The proposed device has good prospects for use for early diagnostics of various diseases.
Double-beta processes play a key role in the exploration of neutrino and weak interaction properties, and in the searches for effects beyond the standard model. During the last half century many attempts were undertaken to search for double-beta decay with emission of two electrons, especially for its neutrinoless mode 0ν2β−, the latter having still not been observed. Double-electron capture (2EC) was not yet in focus because of its in general lower transition probability. However, the rate of neutrinoless double-electron capture 0ν2EC can experience a resonance enhancement by many orders of magnitude when the initial and final states are energetically degenerate. In the resonant case, the sensitivity of the 0ν2EC process can approach the sensitivity of the 0ν2β− decay in the search for the Majorana mass of neutrinos, right-handed currents, and other new physics. An overview of the main experimental and theoretical results obtained during the last decade in this field is presented. The experimental part outlines search results of 2EC processes and measurements of the decay energies for possible resonant 0ν2EC transitions. An unprecedented precision in the determination of decay energies with Penning traps has allowed one to refine the values of the degeneracy parameter for all previously known near-resonant decays and has reduced the rather large uncertainties in the estimate of the 0ν2EC half-lives. The theoretical part contains an updated analysis of the electron shell effects and an overview of the nuclear-structure models, in which the nuclear matrix elements of the 0ν2EC decays are calculated. One can conclude that the decay probability of 0ν2EC can experience a significant enhancement in several nuclides.
[Introduction] This work is a study of the influence of shell effects on the formation of binary fragments in damped collision. We have investigated binary reaction channels of the composite system with Z = 108 produced in the reaction 88 Sr + 176 Yb at an energy slightly above the Bass barrier ( E c.m. /E Bass = 1 . 03). Reaction products were detected by using the two-arm time-of-flight spectrometer CORSET at the K130 cyclotron of the Department of Physics, University of Jyv ̈ askyl ̈ a. The mass-energy distribution of primary binary fragments has been measured. For targetlike fragments heavier than 190 u, which correspond to a mass transfer as large as twenty nucleons or more, an enhancement of the yields is observed. This striking result can be ascribed to the proton shells at Z = 28 and 82 and implies the persistence of the shell effects in the formation of reaction fragments even for large mass transfers.
The structural, chemical, and electronic characteristics of graphene grown by thermal decomposition of a singlecrystal SiC substrate in Ar atmosphere are presented. It is shown that this technology allows the creation of high-quality monolayer graphene films with a small fraction of bilayer graphene inclusions. The performance of graphene on SiC as a gas sensor or a biosensor was tested. The sensitivity of gas sensors to NO2 on the order of 1 ppb and that of biosensors to fluorescein with concentration on the order of 1 ng/mL and to bovine serum albumin-fluorescein conjugate with concentration on the order of 1 ng/mL were determined.
Recent studies have shown that charge transport interlayers with low gas permeability can increase the operational lifetime of perovskite solar cells serving as a barrier for migration of volatile decomposition products from the photoactive layer. Herein we present a hybrid hole transport layer (HTL) comprised of p-type polytriarylamine (PTAA) polymer and vanadium(V) oxide (VOx). Devices with PTAA/VOx top HTL reach up to 20% efficiency and demonstrate negligible degradation after 4500 h of light soaking, whereas reference cells using PTAA/MoOx as HTL lose ∼50% of their initial efficiency under the same aging conditions. It was shown that the main origin of the enhanced device stability lies in the higher tolerance of VOx toward MAPbI3 compared to the MoOx interlayer, which tends to facilitate perovskite decomposition. Our results demonstrate that the application of PTAA/VOx hybrid HTL enables long-term operational stability of perovskite solar cells, thus bringing them closer to commercial applications.
Multi-nucleon transfer reactions are nowadays the only known mean to produce neutron-rich nuclei in the Terra Incognita. The closed-shell region N=126 is crucial for both studying shell-quenching in exotic nuclei and the r-process, being its last "waiting-point". The choice of suitable reactions is challenging and a favorable case is 136Xe+208Pb, near the Coulomb barrier, because their neutron shell-closures play a stabilizing role, favoring the proton-transfer from lead to xenon. TOF-TOF data were analyzed to reconstruct the mass-energy distribution of the primary fragments. Preliminary results of an experiment held at Laboratori Nazionali di Legnaro with PRISMA, aimed at A and Z identification of the products, will be shown.
Background: Observation of asymmetric fission of 180Hg has led to intensive theoretical and experimental studies of fission of neutron-deficient nuclei in the lead region. Purpose: The study of asymmetric and symmetric fission modes of 180,190Hg and 184,192,202Pb nuclei. Methods: Mass-energy distributions of fission fragments of 180,190Hg and 184Pb formed in the 36Ar+144,154Sm and 40Ca+144Sm reactions, respectively, at energies near the Coulomb barrier have been measured using the double-arm time-of-flight spectrometer CORSET and compared with previously measured 192,202Pb isotopes produced in the 48Ca+144,154Sm reactions. The mass distributions for 180,190Hg and 184,192,202Pb together with old data for 187Ir, 195Au, 198Hg, 201Tl, 205,207Bi, 210Po, and 213At [J. Nucl. Phys. 53, 1225 (1991)] have been decomposed into symmetric and asymmetric fission modes. The total kinetic-energy distributions for different fission fragment mass regions have been analyzed for 180,190Hg and 184Pb. Results: The stabilization role of proton numbers at Z≈36, 38, Z≈45, 46, and Z=28/50 in asymmetric fission of excited preactinide nuclei has been observed. The high (≈145−MeV) and the low (≈128−MeV) energy components have been found in the total kinetic-energy distributions of 180,190Hg fission fragments corresponding to the fragments with proton numbers near Z≈46 and Z≈36, respectively. In the case of fission of 184Pb only the low-energy component (≈135MeV) for the fragments with masses corresponding to the proton numbers Z≈36 and 46 has been found. Conclusions: The studied properties of asymmetric fission of 180,190Hg and 184,192,202Pb nuclei point out the existence of well deformed proton shell at Z≈36 and less deformed proton shell at Z≈46.
Reaction products from the system 136Xe+208Pb at 136Xe ions laboratory energies of 700, 870, and 1020 MeV were studied by two-body kinematics and by a catcher-foil activity analysis to explore the theoretically proposed suitability of such reaction as a means to produce neutron-rich nuclei in the neutron shell closure N=126. Cross sections for products heavier than 208Pb were measured and were found sensibly larger than new theoretical predictions. Transfers of up to 16 nucleons from Xe to Pb were observed.
Neutron-rich isotopes of heavy nuclei are until now poorly studied. In this work we investigate neutron-rich osmium isotopes produced in multi-nucleon transfer reactions. The reaction 136Xe+208Pb at energy near Coulomb barrier is used for production of osmium isotopes. The CORSAR-V setup is used to record the characteristics of osmium isotopes. The separation of the reaction products is based on their respective volatility. Experimental results are presented and discussed.
Background: The formation of superheavy nuclei in fusion reactions is suppressed by a competing quasifission process. The competition between the formation of the compound nucleus and the quasifission depends strongly on the reaction entrance channel. Purpose: The investigation of fission and quasifission processes in the formation of Z=120 superheavy composite systems in the 52,54Cr+248Cm and 68Zn+232Th reactions, and their comparison with the 64Ni+238U reaction at energies in the vicinity of the Coulomb barrier. Methods: Mass-energy distributions of fissionlike fragments formed in the reactions 52,54Cr+248Cm and 68Zn+232Th at energies near the Coulomb barrier were measured using the double-arm time-of-flight spectrometer CORSET. Results: Capture cross sections for the reactions under investigation were measured. The most probable fragment masses and total kinetic energies as well as their variances in dependence on the interaction energy were studied for asymmetric and symmetric fragments. The fusion probabilities were estimated from the analysis of mass-energy distributions. Conclusions: The estimated fusion probability drops down by a factor of 103 in the 54Cr+248Cm reaction compared to the reactions of 48Ca ions with actinides. Among the studied reactions, the 54Cr+248Cm is the most favorable one for the production of the superheavy element with Z=120.
We explore the 2013 Planck likelihood function with a high-precision multi-dimensional minimizer (Minuit). This allows a refinement of the ΛCDM best-fit solution with respect to previously-released results, and the construction of frequentist confidence intervals using profile likelihoods. The agreement with the cosmological results from the Bayesian framework is excellent, demonstrating the robustness of the Planck results to the statistical methodology. We investigate the inclusion of neutrino masses, where more significant differences may appear due to the non-Gaussian nature of the posterior mass distribution. By applying the Feldman-Cousins prescription, we again obtain results very similar to those of the Bayesian methodology. However, the profile-likelihood analysis of the cosmic microwave background (CMB) combination (Planck+WP+highL) reveals a minimum well within the unphysical negative-mass region. We show that inclusion of the Planck CMB-lensing information regularizes this issue, and provide a robust frequentist upper limit ∑ mν ≤ 0.26 eV (95% confidence) from the CMB+lensing+BAO data combination.