Rotational coherence imaging and control for CN molecules through time-frequency resolved coherent anti-Stokes Raman scattering
Finna-arvio
Rotational coherence imaging and control for CN molecules through time-frequency resolved coherent anti-Stokes Raman scattering
jcptutka.pdf
(Jyväskylän yliopisto - JYX)
Numerical wave packet simulations are performed for studying coherent anti-Stokes Raman scattering (CARS) for CN radicals. Electronic coherence is created by femtosecond laser pulses between the X²Σ and B²Σ states. Due to the large energy separation of vibrational states, the wave packets are superpositions of rotational states only. This allows for a specially detailed inspection of the second- and third-order coherences by a two-dimensional imaging approach. We present the time-frequency domain images to illustrate the intra- and intermolecular interferences, and discuss the procedure to rationally control and experimentally detect the interferograms in solid Xe environment.
Tallennettuna:
Kieli |
englanti |
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Sarja | The Journal of Chemical Physics, 22 |
Aiheet | |
ISSN |
0021-9606 |