cis,cis,cis-(Acetato-k2O,O ́)bis[1,2-bis- (diphenylphosphanyl)ethane-k2P,P ́]- ruthenium(II) 0.75-trifluoromethanesulfonate 0.25-chloride
Finna-arvio
cis,cis,cis-(Acetato-k2O,O ́)bis[1,2-bis- (diphenylphosphanyl)ethane-k2P,P ́]- ruthenium(II) 0.75-trifluoromethanesulfonate 0.25-chloride
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actacrystallogr2013e69m226valkonen.pdf
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In the title RuII carboxylate compound, [Ru(C₂H₃O₂)(C₂₆H₂₄P₂)₂](CF₃O₃S)₀.₇₅Cl₀.₂₅, the distorted tris-bidentate octahedral stereochemistry about the RuII atom in the complex cation comprises four P-atom donors from two 1,2-bis(diphenylphosphanyl)ethane ligands [Ru-P = 2.2881 (13)-2.3791 (13) Å] and two O-atom donors from the acetate ligand [Ru-O = 2.191 (3) and 2.202 (3) Å]. The disordered counter-anions are located on the same site in the structure in a 3:1 ratio, the expanded formula comprising four complex cations, three trifluoromethanesulfonate anions and one chloride anion, with two such formula units in the unit cell.
Tallennettuna:
| Kieli |
englanti |
|---|---|
| Sarja | Acta Crystallographica Section E : Structure Reports Online, 4 |
| Aiheet | |
| ISSN |
1600-5368 |