This article gives an overview on the decay spectroscopy of T Z  = − 3/2 nuclei 23Al, 31Cl, and 41Ti performed at the Ion Guide Isotope Separator On-Line (IGISOL) facility. The results of the IGISOL experiments are compared to the experimental results that have been published since. The isobaric multiplet mass equation (IMME) has been studied for the T = 3/2 quartets at A = 23 and A = 31. For 41Ti, a detailed comparison to the Gamow–Teller strengths obtained for the analog transitions via charge-exchange reactions has been done. Further improvements in the experimental instrumentation and methods and possible implementations for studying T Z  = − 3/2 nuclei at the new IGISOL facility are discussed.