Decay properties of neutron-deficient exotic nuclei close to A=80 have been investigated at the IGISOL facility. The studied nuclei, 81Y, 81Sr, 81mKr, 85Nb, 85Zr, 86Mo and 86Nb, were produced by a 32S beam from the Jyväskylä isochronous cyclotron on 54Fe and natNi targets. The internal conversion coefficient for a 190.5 keV isomeric transition in 81mKr has been measured and the internal transition rate has been determined. The internal transition rate has been used to estimate a neutrino capture rate on 81Br, which yields a log ft of 5.13±0.09 for the reaction 81Br( ν, e-)81mKr. A new isomer with a half-life of 3.3±0.9 s has been observed in 85Nb. The existence of an earlier reported isomer with a half-life of 56 s in 86Nb has not been confirmed.