Asymmetric [N–I–N]+ halonium complexes
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Asymmetric [N–I–N]+ halonium complexes
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(Jyväskylän yliopisto - JYX)
The first asymmetric halogen-bonded iodonium complexes [I(py)(4-DMAP)]PF6 (2c) and [I(py)(4-Etpy)]PF6 (2e) were prepared via [N-Ag-N]+ → [N-I-N]+ cation exchange of their analogous 2-coordinate silver complexes. The complexes were characterised by 1H and 1H-15N HMBC NMR spectroscopy, and single crystal X-ray crystallography.
Tallennettuna:
Kieli |
englanti |
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Sarja | Chemical Communications, 60 |
Aiheet | |
ISSN |
1359-7345 |